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Langmuir-Schaefer films for aligned carbon nanotubes functionalized with a conjugate polymer and photoelectrochemical response enhancement.

Identifieur interne : 000126 ( Main/Exploration ); précédent : 000125; suivant : 000127

Langmuir-Schaefer films for aligned carbon nanotubes functionalized with a conjugate polymer and photoelectrochemical response enhancement.

Auteurs : RBID : pubmed:24328296

Abstract

Single-walled carbon nanotubes (SWCNTs) were suspended in 1,2-dichloroethane by noncovalent functionalization with a low-band-gap conjugated polymer 1 alternating dialkoxyphenylene-bisthiophene units with benzo[c][2,1,3]thiadiazole monomeric units. The suspended 1/SWCNT blend was transferred onto different solid substrates by the Langmuir-Schaefer deposition method, resulting in films with a high percentage of aligned nanotubes. Photoelectrochemical characterization of 1/SWCNT thin films on indium-tin oxide showed the benefits of SWCNT alignment for photoconversion efficiency.

DOI: 10.1021/am403656k
PubMed: 24328296

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<div type="abstract" xml:lang="en">Single-walled carbon nanotubes (SWCNTs) were suspended in 1,2-dichloroethane by noncovalent functionalization with a low-band-gap conjugated polymer 1 alternating dialkoxyphenylene-bisthiophene units with benzo[c][2,1,3]thiadiazole monomeric units. The suspended 1/SWCNT blend was transferred onto different solid substrates by the Langmuir-Schaefer deposition method, resulting in films with a high percentage of aligned nanotubes. Photoelectrochemical characterization of 1/SWCNT thin films on indium-tin oxide showed the benefits of SWCNT alignment for photoconversion efficiency.</div>
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